Hi,欢迎进入乐研化学商城!

   在线客服 | 我的乐研 |    购物车 | | 注册有礼  

首页 > 关于乐研 > GHS危害和防护代码

GHS危害和防护代码

HAZARD AND PRECAUTIONARY STATEMENTS


blob.png 

Hazard Statements

(There are 72 individual and 17 combined Hazard statements)



Physical hazards
H200Unstable   explosives.
H201Explosive; mass   explosion hazard.
H202Explosive,   severe projection hazard.
H203Explosive;   fire, blast or projection hazard.
H204Fire or   projection hazard.
H205May mass   explode in fire.
H220Extremely   flammable gas.
H221Flammable gas.
H222Extremely   flammable aerosol.
H223Flammable   aerosol.
H224Extremely   flammable liquid and vapour.
H225Highly   flammable liquid and vapour.
H226Flammable   liquid and vapour.
H227Combustible   liquid.
H228Flammable   solid.
H240Heating may   cause an explosion.
H241Heating may   cause a fire or explosion.
H242Heating may   cause a fire.
H250Catches fire   spontaneously if exposed to air.
H251Self-heating:   may catch fire.
H252Self-heating in   large quantities; may catch fire.
H260In contact with   water releases flammable gases which may ignite spontaneously.
H261In contact with   water releases flammable gas.
H270May cause or   intensify fire; oxidizer.
H271May cause fire   or explosion; strong oxidizer.
H272May intensify   fire; oxidizer.
H280Contains gas   under pressure; may explode if heated.
H281Contains   refrigerated gas; may cause cryogenic burns or injury.
H290May be   corrosive to metals.


Environmental Hazards
H400Very toxic to   aquatic life.
H401Toxic to   aquatic life.
H402Harmful to   aquatic life.
H410Very toxic to   aquatic life with long lasting effects.
H411Toxic to   aquatic life with long lasting effects.
H412Harmful to   aquatic life with long lasting effects.
H413May cause long   lasting harmful effects to aquatic life.
H420Harms public   health and the environment by destroying ozone in the upper atmospere.
European Union Hazard Statements
EUH001  Explosive when   dry.
EUH006Explosive with   or without contact with air.
EUH014Reacts   violently with water.
EUH018In use may form   flammable/explosive vapour-air mixture.
EUH018aIn use may form   explosive vapour-air mixture.
EUH018bIn use may form   flammable vapour-air mixture.
EUH019May form   explosive peroxides.
EUH029Contact with   water liberates toxic gas.
EUH030Can become   highly flammable in use.
EUH031Contact with   acids liberates toxic gas.
EUH032Contact with   acids liberates very toxic gas.
EUH044Risk of   explosion if heated under confinement.
EUH059Hazardous to   the ozone layer.
EUH066Repeated   exposure may cause skin dryness or cracking.
EUH070Toxic by eye   contact.
EUH071Corrosive to   the respiratory tract.
EUH201Contains lead.   Should not be used on surfaces liable to be chewed or sucked by children.   Warning! Contains lead.
EUH201AWarning!   Contains lead.
EUH202Cyanoacrylate.   Danger. Bonds skin and eyes in seconds. Keep out of the reach of children.
EUH203Contains   chromium (VI). May produce an allergic reaction.
EUH204Contains   isocyanates. See information supplied by the manufacturer.
EUH205Contains epoxy   constituents. See information supplied by the manufacturer.
EUH206Warning! Do not   use together with other products. May release dangerous gases (chlorine).
EUH207Warning!   Contains cadmium. Dangerous fumes are formed during use. See information   supplied by the manufacturer.
Comply   with the safety instructions.
EUH207-EGWarning!   Contains cadmium. Dangerous fumes are formed during use. See information   supplied by the manufacturer.
Comply   with the safety instructions.
EUH208Contains (name   of sensitising substance). May produce an allergic reaction.
EUH208-EGContains (name   of sensitising substance). May produce an allergic reaction.
EUH209Can become   highly flammable in use.
EUH209aCan become   highly flammable in use.
EUH209bCan become   flammable in use.
EUH209ACan become   flammable in use.
EUH210Safety data   sheet available on request.
EUH401To avoid risks   to human health and the environment, comply with the instructions for use.

Precautionary Statements

(There are 116 individual and 33 combined Precautionary statements)


Precautionary statements - General
P101If medical advice is needed ,have product container or label at   hand.
P102Keep out of reach of children.
P103Read label before use.
Precautionary statements - Prevention
P201Obtain special   instructions before use.
P202Do not handle   until all safety precautions have been read and understood.
P210Keep away from   heat/sparks/open flames/hot surfaces.—— No smoking.
P211Do not spray on   an open flame or other ignition source.
P220Keep/Store away   from clothing/..../combustible materials.
P221Take any   precaution to avoid mixing with combustibles/....
P222Do not allow   contact with air.
P223Keep away from   any possible contact with water, because of violent reaction and possible   flash fire.
P230Keep wetted with   ....
P231Handle under   inert gas.
P232Protect from   moisture.
P233Keep container   tightly closed.
P234Keep only in   original container.
P235Keep cool.
P240Ground/bond   container and receiving equipment.
P241Use   explosion-proof electrical/ventilating/lighting/..../equipment.
P242Use only   non-sparking tools.
P243Take   precautionary measures against static discharge.
P244Keep reduction   valves free from grease and oil.
P250Do not subject   to grinding/shock/..../friction.
P251Pressurized   container: Do not pierce or burn, even after use.
P260Do not breathe   dust/fume/gas/mist/vapours/spray.
P261Avoid breathing   dust/fume/gas/mist/vapours/spray.
P262Do not get in   eyes, on skin, or on clothing.
P263Avoid contact   during pregnancy/while nursing.
P264Wash hands   thoroughly after handling.
P264Wash skin   thouroughly after handling.
P270Do not eat,   drink or smoke when using this product.
P271Use only   outdoors or in a well-ventilated area.
P272Contaminated   work clothing should not be allowed out of the workplace.
P273Avoid release to   the environment.
P280Wear protective   gloves/protective clothing/eye protection/face protection.
P281Use personal   protective equipment as required.
P282Wear cold   insulating gloves/face shield/eye protection.
P283Wear fire/flame   resistant/retardant clothing.
P284Wear respiratory   protection.
P285In case of   inadequate ventilation wear respiratory protection.
P231+P232Handle under   inert gas. Protect from moisture.
P235+P410Keep cool.   Protect from sunlight.
Precautionary statements - Response
P301IF SWALLOWED:
P304IF INHALED:
P305IF IN EYES:
P306IF ON CLOTHING:
P307IF exposed:
P308IF exposed or   concerned:
P309IF exposed or if   you feel unwell:
P310Immediately call   a POISON CENTER or doctor/physician.
P311Call a POISON   CENTER or doctor/physician.
P312Call a POISON   CENTER or doctor/physician if you feel unwell.
P313Get medical   advice/attention.
P314Get medical   advice/attention if you feel unwell.
P315Get immediate   medical advice/attention.
P320Specific   treatment is urgent (see .... on this label).
P321Specific   treatment (see .... on this label).
P322Specific   measures (see .... on this label).
P330Rinse mouth.
P331Do NOT induce   vomiting.
P332IF SKIN   irritation occurs:
P333If skin   irritation or rash occurs:
P334Immerse in cool   water/wrap n wet bandages.
P335Brush off loose   particles from skin.
P336Thaw frosted   parts with lukewarm water. Do not rub affected area.
P337If eye   irritation persists:
P338Remove contact   lenses, if present and easy to do. Continue rinsing.
P340Remove victim to   fresh air and keep at rest in a position comfortable for breathing.
P341If breathing is   difficult, remove victim to fresh air and keep at rest in a position   comfortable for breathing.
P342If experiencing   respiratory symptoms:
P350Gently wash with   plenty of soap and water.
P351Rinse cautiously   with water for several minutes.
P352Wash with plenty   of soap and water.
P353Rinse skin with   water/shower.
P360Rinse   immediately contaminated clothing and skin with plenty of water before   removing clothes.
P361Remove/Take off   immediately all contaminated clothing.
P362Take off   contaminated clothing and wash before reuse.
P363Wash   contaminated clothing before reuse.
P370In case of fire:
P371In case of major   fire and large quantities:
P372Explosion risk   in case of fire.
P373DO NOT fight   fire when fire reaches explosives.
P374Fight fire with   normal precautions from a reasonable distance.
P376Stop leak if   safe to do so. Oxidising gases (section 2.4) 1
P377Leaking gas   fire: Do not extinguish, unless leak can be stopped safely.
P378Use .... for   extinction.
P380Evacuate area.
P381Eliminate all   ignition sources if safe to do so.
P390Absorb spillage   to prevent material damage.
P391Collect   spillage. Hazardous to the aquatic environment
P301+P310IF SWALLOWED:   Immediately call a POISON CENTER or doctor/physician.
P301+P312IF SWALLOWED:   call a POISON CENTER or doctor/physician IF you feel unwell.
P301+P330+P331IF SWALLOWED:   Rinse mouth. Do NOT induce vomiting.
P302+P334IF ON SKIN:   Immerse in cool water/wrap in wet bandages.
P302+P350IF ON SKIN:   Gently wash with plenty of soap and water.
P302+P352IF ON SKIN: wash   with plenty of soap and water.
P303+P361+P353IF ON SKIN (or   hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with   water/shower.
P304+P312IF INHALED: Call   a POISON CENTER or doctor/physician if you feel unwell.
P304+P340IF INHALED:   Remove victim to fresh air and Keep at rest in a position comfortable for   breathing.
P304+P341IF INHALED: If   breathing is difficult, remove victim to fresh air and keep at rest in a   position comfortable for breathing.
P305+P351+P338
P306+P360IF ON CLOTHING:   Rinse Immediately contaminated CLOTHING and SKIN with plenty of water before   removing clothes.
P307+P311IF exposed: call   a POISON CENTER or doctor/physician.
P308+P313IF exposed or   concerned: Get medical advice/attention.
P309+P311IF exposed or if   you feel unwell: call a POISON CENTER or doctor/physician.
P332+P313IF SKIN   irritation occurs: Get medical advice/attention.
P333+P313IF SKIN   irritation or rash occurs: Get medical advice/attention.
P335+P334Brush off loose   particles from skin. Immerse in cool water/wrap in wet bandages.
P337+P313IF eye   irritation persists: Get medical advice/attention.
P342+P311IF experiencing   respiratory symptoms: call a POISON CENTER or doctor/physician.
P370+P376in case of fire:   Stop leak if safe to Do so.
P370+P378In case of fire:   Use .... for extinction.
P370+P380in case of fire:   Evacuate area.
P370+P380+P375in case of fire:   Evacuate area. Fight fire remotely due to the risk of explosion.
P371+P380+P375in case of major   fire and large quantities: Evacuate area. Fight fire remotely due to the risk   of explosion.
Precautionary statements —— Storage
P401Store ....
P402Store in a dry   place.
P403Store in a   well-ventilated place.
P404Store in a   closed container.
IF IN EYES:Rinse cautiously   with water for several minutes. Remove contact lenses, if present and easy to   do. Continue rinsing.
P405Store locked up.
P406Store in   corrosive resistant/.... container with a resistant inner liner.
P407Maintain air gap   between stacks/pallets.
P410Protect from   sunlight.
P411Store at   temperatures not exceeding .... oC/....oF.
P412Do not expose to   temperatures exceeding 50 oC/ 122 oF.
P413Store bulk   masses greater than .... kg/....lbs at temperatures not exceeding ....   oC/....oF.
P420Store away from   other materials.
P422Store contents   under ....
P402+P404Store in a dry   place. Store in a closed container.
P403+P233Store in a   well-ventilated place. Keep container tightly closed.
P403+P235Store in a   well-ventilated place. Keep cool.
P410+P403Protect from   sunlight. Store in a well-ventilated place.
P410+P412Protect from   sunlight. Do not expose to temperatures exceeding 50 oC/122oF.
P411+P235Store at   temperatures not exceeding .... oC/....oF. Keep cool.
Precautionary statements —— Disposal
P501Dispose of contents/container to....
P502Refer to manufacturer/supplier for information on   recovery/recycling


PICTOGRAMS AND HAZARD CODES

Compared to the current EU system the most noticeable change are the pictograms (formerly: hazard symbols). While the most of the GHS pictograms
have an equivalent in the old system, the pictograms GHS 04, GHS 07 and GHS 08 are completely new.

The GHS System is built on 16 physical, 10 health and 3 environmental hazard classes and comprises the following communication elements:


9   Pictograms

Description

Pictogram

Hazard class and hazard category:

说明: http://www.macklin.cn/static/images/new_ghs_wps_clip_image-10969.png

Exploding Bomb
    GHS01

blob.png

Unstable explosives
    Explosives of Divisions 1.1, 1.2, 1.3, 1.4
    Self reactive substances and mixtures, Types A,B
    Organic peroxides, Types A,B

说明: http://www.macklin.cn/static/images/new_ghs_wps_clip_image-10969.png

Flame
    GHS02

blob.png

Flammable gases, category 1
    Flammable aerosols, categories 1,2
    Flammable liquids, categories 1,2,3
    Flammable solids, categories 1,2
    Self-reactive substances and mixtures, Types B,C,D,E,F
    Pyrophoric liquids, category 1
    Pyrophoric solids, category 1
    Self-heating substances and mixtures, categories 1,2
    Substances and mixtures, which in contact with water,
    emit flammable gases, categories 1,2,3
    Organic peroxides, Types B,C,D,E,F

说明: http://www.macklin.cn/static/images/new_ghs_wps_clip_image-10969.png

Flame Over Circle
    GHS03

blob.png

Oxidizing gases, category 1
    Oxidizing liquids, categories 1,2,3

说明: http://www.macklin.cn/static/images/new_ghs_wps_clip_image-10969.png

Gas Cylinder
    GHS04

blob.png

Gases under pressure:
    - Compressed gases
    - Liquefied gases
    - Refrigerated liquefied gases
    - Dissolved gases

说明: http://www.macklin.cn/static/images/new_ghs_wps_clip_image-10969.png

Corrosion
    GHS05

blob.png

Corrosive to metals, category 1
    Skin corrosion, categories 1A,1B,1C
    Serious eye damage, category 1

说明: http://www.macklin.cn/static/images/new_ghs_wps_clip_image-10969.png

Skull and Crossbones
    GHS06

blob.png

Acute toxicity (oral, dermal, inhalation),     categories 1,2,3

说明: http://www.macklin.cn/static/images/new_ghs_wps_clip_image-10969.png

Exclamation Mark
    GHS07

blob.png

Acute toxicity (oral, dermal, inhalation),     category 4
    Skin irritation, category 2
    Eye irritation, category 2
    Skin sensitisation, category 1
    Specific Target Organ Toxicity – Single exposure, category 3

说明: http://www.macklin.cn/static/images/new_ghs_wps_clip_image-10969.png

Health Hazard
    GHS08

blob.png

Respiratory sensitization, category 1
    Germ cell mutagenicity, categories 1A,1B,2
    Carcinogenicity, categories 1A,1B,2
    Reproductive toxicity, categories 1A,1B,2
    Specific Target Organ Toxicity – Single exposure, categories 1,2
    Specific Target Organ Toxicity – Repeated exposure, categories 1,2
    Aspiration Hazard, category 1

说明: http://www.macklin.cn/static/images/new_ghs_wps_clip_image-10969.png

Environment
    GHS09

blob.png

Hazardous to the aquatic environment
    - Acute hazard, category1
    - Chronic hazard, categories 1,2

点此下载:GSH-zok.docx